Chuck's World - An inside look at character development and casting sessions
Chuck on Chuck - Series Stars Zachary Levi and Joshua Gomez join creators Josh Schwartz and Chris Fedek for some point/counterpoint
Chuck vs. the Chuckles - aka: The Gag Reel
Chuck's Online World - a gallery of web originated mini-featurettes
Chuck: Season 2
Truth, Spies and Regular Guys: Exploring the Mythology of Chuck
John Casey Presents: So You Want to Be a Deadly Spy?
Dude in Distress: Explore Some of This Season's Best Action Sequences
Chuck: A Real-Life Captain Awesome's Tips for Being Awesome
Chuck Versus the Webisodes: Web-Originated Minifeaturettes
Declassified Scenes
Gag Reel
Chuck: Season 3
The Jeffster Revolution: The Definitive Mockumentary
Gag Reel
Declassified Scenes
Chuck-Fu…and Dim Sum: Becoming a Spy Guy
Chuck: Season 4
Buy Hard: The Jeff and Lester Story : The 5-Episode Chronicle of Jeff and Lester's Quest for an Elusive Video Game
Spying on the Chuck Cast - Operation Gomez: Joshua Gomez Shows Off His Newfound Spy Skills
Declassified Scenes
Chuck Versus Directing: Zachary Levi Takes Charge on Chuck Versus the Leftovers
Gag Reel
BLU-RAY EXCLUSIVE: The Top Secret Chuckipedia Interactive Experience
Chuck: Season 5
Sandwiches and Superfans: The Saving of a Show (featurette)
Extended version of the series finale episode Chuck vs. The Final Episode - An intimate look at the climactic shooting of the final episode (featurette)
Scoring the World of Chuck (featurette)
Full versions of the Buy-More TV commercials with Big Mike and Captain Awesome
2 full-length audio commentaries on final 2 episodes by Executive Producers and key cast members